.

Mark Humphrey - Selected Publications#


C. Wu, X. Jiang, Z. Wang, H. Sha, Z. Lin, Z. Huang, X. Long, M.G. Humphrey, and C. Zhang, Angew. Chem. Int. Ed., 2021, 60, 14806-14810.
UV Solar-Blind-Region Phase-Matchable Optical Nonlinearity and Anisotropy in a π‑Conjugated Cation-Containing Phosphate

T. Wu, C. Wu, X. Jiang, Z. Wang, L. Lin, Z. Lin, Z. Huang, X. Long, M.G. Humphrey, and C. Zhang, J. Am. Chem. Soc., 2021, 143, 4138-4142.
Large Second-Harmonic Response and Giant Birefringence of Ce(SO4)F2 Induced by Highly Polarizable Polyhedra

C. Wu, X. Jiang, Z. Wang, Z. Lin, Z. Huang, X. Long, M.G. Humphrey, and C. Zhang, Angew. Chem. Int. Ed., 2021, 60, 3464-3468.
Giant Optical Anisotropy in the UV-Transparent 2D Nonlinear Optical Material Sc(IO3)2(NO3).

A. Wang, J. Ye, M.G. Humphrey and C. Zhang, Adv. Mater., 2018, 30, 1705704-1 – 1705704-9.
Graphene and Carbon-Nanotube Nanohybrids Covalently Functionalized by Porphyrins and Phthalocyanines for Optoelectronic Properties

P.V. Simpson, L.A. Watson, A. Barlow, G. Wang, M.P. Cifuentes and M.G. Humphrey, Angew. Chem. Int. Ed., 2016, 55, 2387-2391.
Record Multiphoton-Absorption Cross-Sections by Dendrimer Organometalation

T. Schwich, M.P. Cifuentes, P.A. Gugger, M. Samoc and M.G. Humphrey, Adv. Mater., 2011, 23, 1433-1435.
Electronic, Molecular Weight, Molecular Volume, and Financial Cost-Scaling and Comparison of Two-Photon Absorption Efficiency in Disparate Molecules

C. Zhang, T. Matsumoto, M. Samoc, S. Meng, T.C. Corkery, S. Petrie, R. Stranger, J. Zhang, M.G. Humphrey and K. Tatsumi, Angew. Chem. Int. Ed., 2010, 49, 4209-4212.
Dodecanuclear Ellipse and Decanuclear Wheel Nickel(II) Thiolato Clusters with Efficient fs Nonlinear Absorption

B. Babgi, L. Rigamonti, M.P. Cifuentes, T.C. Corkery, M.D. Randles, T. Schwich, S. Petrie, R. Stranger, A. Teshome, I. Asselberghs, K. Clays, M. Samoc, and M.G. Humphrey, J. Am. Chem. Soc., 2009, 131, 10293-10307.
Length Dependent Convergence and Saturation Behavior of Electrochemical, Linear Optical, Quadratic and Cubic Nonlinear Optical Properties of Dipolar Alkynylruthenium Complexes with Oligo(phenyleneethynylene) Bridges

K.A. Green, M.P. Cifuentes, T.C. Corkery, M. Samoc and M.G. Humphrey, Angew. Chem. Int. Ed., 2009, 48, 7867-7870.
Switching the Cubic Nonlinear Optical Properties of an Electro-, Halo-, and Photochromic Ruthenium Alkynyl Complex Across Six States

R.L. Roberts, T. Schwich, T.C. Corkery, M.P. Cifuentes, K.A. Green, J.D. Farmer, P.J. Low, T.B. Marder, M. Samoc and M.G. Humphrey, Adv. Mater., 2009, 21, 2318-2322.
Organometallic Complexes for Nonlinear Optics. 45. Dispersion of the Third-order Nonlinear Optical Properties of Triphenylamine-cored Alkynylruthenium Dendrimers

C. Zhang, Y. Cao, J. Zhang, S. Meng, T. Matsumoto, Y. Song, J. Ma, Z. Chen, K. Tatsumi, and M.G. Humphrey, Adv. Mater., 2008, 20, 1870-1875.
Modulation of Third-Order Nonlinear Optical Properties by Backbone Modification at Polymeric Pillared-layer Heterometallic Clusters

N. Gauthier, G. Argouarch, F. Paul, M.G. Humphrey, L. Toupet, S. Ababou-Girard, H. Sabbah, P. Hapiot and B. Fabre, Adv. Mater., 2008, 20, 1952-1956.
Silicon Surface-Bound Redox-Active Conjugated Wires Derived From Mono- and Dinuclear Iron(II) and Ruthenium(II) Oligo(phenyleneethynylene) Complexes

G.T. Dalton, M.P. Cifuentes, S. Petrie, R. Stranger, M.G. Humphrey and M. Samoc, J. Am. Chem. Soc., 2007, 129, 11882-11883.
Independent Switching of Cubic Nonlinear Optical Properties in a Ruthenium Alkynyl Cruciform Complex by Employing Protic and Electrochemical Stimuli

M. Samoc, J.P. Morrall, G.T. Dalton, M.P. Cifuentes and M.G. Humphrey, Angew. Chem. Int. Ed., 2007, 46, 731-733.
Two-Photon and Three-Photon Absorption in an Organometallic Dendrimer

M.P. Cifuentes, C.E. Powell, J.P. Morrall, A.M. McDonagh, N.T. Lucas, M.G. Humphrey, M. Samoc, S. Houbrechts, I. Asselberghs, K. Clays, A. Persoons and T. Isoshima, J. Am. Chem. Soc., 2006, 128, 10819-10832.
Electrochemical, Spectroelectrochemical, and Molecular Quadratic and Cubic Nonlinear Optical Properties of Alkynylruthenium Dendrimers

M. Samoc, N. Gauthier, M.P. Cifuentes, F. Paul, C. Lapinte and M.G. Humphrey, Angew. Chem. Int. Ed., 2006, 45, 7376-7379.
Electrochemical Switching of the Cubic Nonlinear Optical Properties of an Aryldiethynyl-linked Heterobimetallic Complex Between Three Distinct States

C.E. Powell, J.P. Morrall, S.A. Ward, M.P. Cifuentes, E.G.A. Notaras, M. Samoc and M.G. Humphrey, J. Am. Chem. Soc., 2004, 126, 12234-12235.
Dispersion of the Third-order Nonlinear Optical Properties of an Organometallic Dendrimer

C.E. Powell, M.P. Cifuentes, J.P.L. Morrall, R. Stranger, M.G. Humphrey, M. Samoc, B. Luther-Davies and G.A. Heath, J. Am. Chem. Soc., 2003, 125, 602-610.
Organometallic Complexes for Nonlinear Optics. 30. Electrochromic Linear and Nonlinear Optical Properties of Alkynylbis(diphosphine)ruthenium Complexes

N.T. Lucas, J.P. Blitz, S. Petrie, R. Stranger, M.G. Humphrey, G.A. Heath and V. Otieno-Alego, J. Am. Chem. Soc., 2002, 124, 5139-5153.
Mixed-Metal Cluster Chemistry. 19. Crystallographic, Spectroscopic, Electrochemical, Spectroelectrochemical and Theoretical Studies of Systematically Varied Tetrahedral Group 6-Iridium Clusters

A.M. McDonagh, M.G. Humphrey, M. Samoc, B. Luther-Davies, S. Houbrechts, T. Wada, H. Sasabe and A. Persoons, J. Am. Chem. Soc., 1999, 121, 1405-1406.
Organometallic Complexes for Nonlinear Optics. 16. Second and Third Order Optical Nonlinearities of Octopolar Alkynylruthenium Complexes

I.R. Whittall, M.G. Humphrey, M. Samoc and B. Luther-Davies, Angew. Chem. Int. Ed. Engl., 1997, 36, 370-371.
Organometallic Complexes for Nonlinear Optics. Part 9. Molecular Cubic Hyperpolarizabilities of Systematically Varied (Triphenylphosphine)gold sigma-Arylacetylide Complexes

M.P. Cifuentes, M.G. Humphrey, J.E. McGrady, P. Smith, R. Stranger, K.S. Murray and B. Moubaraki, J. Am. Chem. Soc., 1997, 119, 2647-2655.
High Nuclearity Ruthenium Carbonyl Cluster Chemistry. 5. Electron paramagnetic resonance, magnetic susceptibility, local density functional and electronic spectroscopy studies on (carbido)decaruthenium carbonyl clusters

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